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Adding substituents to the azobenzene rings may lead to minor or major changes in spectroscopic character f particular interest is ortho- or parasubstitution with an electron-donating group (usually an amino, NH2), which results in a new class of compounds In these aminoazobenzenes, the n-p* and p-p* bands are much closer In fact, the n-p* may be completely buried beneath the intense p-p* Although azobenzenes are fairly insensitive to solvent polarity, aminoazobenzene absorption bands shift to higher energy in nonpolar solvents and shift to lower energy in polar solvents Substituting azobenzene at the 4 and 4u positions with an electron-donor and an electron-acceptor (such as an amino and a nitro, NO2, group) leads to a strongly asymmetric electron distribution (often referred to as a push pull substitution pattern) This shifts the p-p* absorption to lower energy, toward the red and past the n-p*.

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This reversed ordering of the absorption bands de nes the third spectroscopic class, the pseudo-stilbenes (in analogy to stilbene, phenyl C=C phenyl) The pseudo-stilbenes are very sensitive to local environment, which can be useful in some applications Especially in condensed phases, the azos are also sensitive to packing and aggregation The p p stacking gives rise to shifts of the absorption spectrum If the azo dipoles have a parallel (head-to-head) alignment, they are called J-aggregates, and give rise to a redshift of the spectrum (bathochromic) as compared with the isolated chromophore If the dipoles are antiparallel (head-to-tail), they are called H-aggregates and lead to a blueshift (hypsochromic) Fluorescence is seen in some aminoazobenzenes and many pseudo-stilbenes but not in azobenzenes, whereas phosphorescence is absent in all the three classes.

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By altering the electron density, the substitution pattern necessarily affects the dipole moment, and in fact all the higher order multipole moments This becomes signi cant in many nonlinear optical (NLO) studies For instance, the chromophore s dipole moment can be used to orient with an applied electric eld (poling), and the higher order moments of course de ne the molecule s nonlinear response (Delaire and Nakatani, 2000) In particular, the strongly asymmetric distribution of the delocalized electrons that results from push pull substitution results in an excellent NLO chromophore integrated for rdlc reports control to generate, create 2d matrix barcode image in rdlc Related: NET QR Code Generating , Generate Code 39 NET , Create Code 128 NET.

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Helmholtz, the electrical double layer has the character of a late condenser, whose plates are represented by homogeneously distributed charge in the metal and ions of the opposite charge lying in a parallel plane in the solution at a minimal distance from the surface of the metal According to modern conceptions, the electron cloud in the metal extends to a certain degree into the region of the layer of solvent molecules in the immediate vicinity of the metal surface In this layer, the dipoles of the solvent molecules are oriented to various degrees towards the metal surface Ions can gather in the solution portion of the interphase as a result of the electrostatic field of the electrode ('electrostatic adsorption') They can also, however, be adsorbed specifically on the electrode through van der Waals, hydrophobic and chemical forces.

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